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3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 18-5798-6 Issue date : 2009/05/22
Version : 2.00 Supersedes date : 2009/04/03
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Corporate Regulatory Services, 3M Canada Company
Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca
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1 Chemical Product and Company Identification
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Tradename:
3M(TM) Scotch-Weld(TM) 2214 Regular Epoxy Adhesive
Product ID:
62-2214-2930-1 62-2214-2932-7 62-2214-2935-0 62-2214-6530-5
62-2214-7530-4 62-2214-8530-3
Intended Use of Product:
Adhesive
Division:
AD - Industrial Adhesives and Tapes Division
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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PHENOL, 4,4'- (1-METHYLETHYLIDENE) 25068-38-6 30 - 60
BIS-, POLYMER WITH (CHLOROMETHYL)
OXIRANE
ALUMINUM PIGMENTS 7429-90-5 15 - 40
Synthetic Elastomer- N.J.T.S. Reg No. Trade Secret 1 - 5
04499600-5706P
EPOXY RESIN 41638-13-5 1 - 5
AMORPHOUS SILICA 67762-90-7 1 - 5
p-Chlorophenyl-Dimethylurea 150-68-5 1 - 5
DICYANDIAMIDE 461-58-5 1 - 5
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1,4-BIS[(2,3-EPOXYPROPOXY)METHYL] 14228-73-0 0.1 - 1.0
CYCLOHEXANE
NOTE:
SYNTHETIC ELASTOMER is a non-hazardous Trade Secret material
according to WHMIS criteria.
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
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3 Hazards Identification
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Critical Hazards:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Moderate Skin Irritation: Signs/symptoms can include localized
redness, swelling, itching, and dryness.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Remove contaminated clothing and shoes. Immediately flush skin with
large amounts of water. Get medical attention. Wash contaminated
clothing and clean shoes before reuse.
Instructions for Inhalation:
If signs/symptoms develop, remove person to fresh air. If
signs/symptoms persist, get medical attention.
Instructions for Ingestion:
Do not induce vomiting unless instructed to do so by medical
personnel. Get medical attention.
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5 Fire Fighting Measures
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Flash point: 248.9 C CC
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition temperature: Not Available
Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents (e.g., dry
chemical, carbon dioxide).
Exposure Hazards during Fire:
No unusual fire or explosion hazards are anticipated.
3M(TM) Scotch-Weld(TM) 2214 Regular Epoxy Adhesive Page 3 of 10
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Combustion Products from Fire:
Aldehydes - During Combustion;
Chlorine - During Combustion;
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Hydrogen Chloride - During Combustion;
Hydrogen Cyanide - During Combustion;
Ammonia - During Combustion;
Oxides of Nitrogen - During Combustion;
Unusual Fire and Explosion Hazards
None known.
Fire Fighting Procedures:
Water may be used to blanket the fire. Wear full protective
equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
NFPA: Health 2
NFPA: Fire 0
NFPA: Reactivity 1
NFPA: Unusual Reaction Hazard none
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6 Accidental Release Measures
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Personal Precautions:
Observe precautions from other sections. Call 3M- HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Evacuate unprotected and untrained personnel from hazard area. The
spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. For large spill, or spills in confined spaces,
provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor
could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode. Contain spill. For
larger spills, cover drains and build dikes to prevent entry into
sewer systems or bodies of water. Working from around the edges of
the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in
sufficient absorbent until it appears dry. Collect as much of the
spilled material as possible. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate
the area with fresh air. Read and follow safety precautions on the
solvent label and MSDS. Collect the resulting residue containing
solution. Place in a closed container approved for transportation
by appropriate authorities. Dispose of collected material as soon
as possible.
3M(TM) Scotch-Weld(TM) 2214 Regular Epoxy Adhesive Page 4 of 10
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7 Handling and Storage
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Storage Requirements:
Keep container closed when not in use.
Incompatible Materials:
Store away from heat;
Store out of direct sunlight.
Store away from oxidizing agents.
Sparks and/or Flames;
Avoid curing large quantities of material to prevent a premature
reaction (exotherm) with production of intense heat and smoke.
Ventilation:
No data available.
Use Instructions:
For industrial or professional use only. Avoid eye contact with
vapours, mists, or spray. Avoid contact with oxidizing agents.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapours, mists, or spray.
The following should be worn alone or in combination, as
appropriate, to prevent eye contact:
Safety glasses with side shields
Indirect vented goggles;
Hand Protection:
Wear appropriate gloves when handling this material.
The following glove material(s) are recommended:
polyethylene/ethylene vinyl alcohol;
polyvinyl alcohol;
Skin Protection:
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin
contact based on the results of an exposure assessment. Consult
with your glove and/or protective clothing manufacturer for
selection of appropriate compatible materials.
Respiratory Protection:
Under normal use conditions, airborne exposures are not expected to
be significant enough to require respiratory protection.
Select one of the following approved respirators based on airborne
concentration of contaminants and in accordance with regulations:
Half facepiece or fullface air-purifying respirator with P100
particulate filters;
Half facepiece or fullface air-purifying respirator with P95
particulate filters;
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Half facepiece or fullface air-purifying respirator with N95
particulate prefilters;
Ingestion (Prevention):
Do not ingest.
Wash hands after handling and before eating.
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
Recommended Ventilation:
Use in a well-ventilated area.
Use general dilution ventilation and/or local exhaust ventilation
to control airborne exposures to below Occupational Exposure Limits
and/or control mist, vapour, or spray. If ventilation is not
adequate, use respiratory protection equipment.
Use with appropriate local exhaust ventilation.
Provide appropriate local exhaust when product is heated.
Provide appropriate local exhaust for cutting, grinding, sanding or
machining.
Ingredient Exposure Data
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PHENOL, 4,4'- (1-METHYLETHYLIDENE) BIS-, POLYMER WITH (CHLOROMETHYL)
OXIRANE (25068-38-6)
LD50 (rat, oral) 11400 mg/kg
LD50 (dermal, rabbit) 23.4 g/kg
LC50 (rat, inhalation/4 hours) > 791 mg/m3
Exposure Limits
No data available.
ALUMINUM PIGMENTS (7429-90-5)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 1 mg/m3 (Respirable) (Table A4)
ACGIH: TWA 5 mg/m3 (as Aluminum) Category: ALUMINUM PYRO POWDERS
Synthetic Elastomer- N.J.T.S. Reg No. 04499600-5706P (Trade Secret)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
EPOXY RESIN (41638-13-5)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
AMORPHOUS SILICA (67762-90-7)
Specific Ingredient Data
LD50 (rat, dermal): > 16 ml/kg
LC50 (rat, inhalation, dust/1hour): 1260 2830 mg/m3
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LD50 (rat, oral) > 64 g/kg
LD50 (dermal, rabbit) > 16 g/kg
LC50 (rat, inhalation/4 hours) 315 - 708 mg/m3
Exposure Limits
CMRG: CEIL 5 mg/m3
p-Chlorophenyl-Dimethylurea (150-68-5)
Specific Ingredient Data
LD50 (rat, dermal): > 2500 mg/kg
LD50 (rat, oral) 1053 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
DICYANDIAMIDE (461-58-5)
LD50 (rat, oral) > 20,000 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
1,4-BIS[(2,3-EPOXYPROPOXY)METHYL]CYCLOHEXANE (14228-73-0)
Specific Ingredient Data
No data available.
LD50 (rat, oral) 2.45 g/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Solid; paste; grey;
Odour Threshold: No data available.
pH: Not applicable
Boiling point/boiling range: >= 260 C
Melting point/melting range: Not applicable
Vapour pressure: Not Available
Water Solubility: Nil
Specific gravity: 1.44 Water=1
Vapour density: Not Available
Volatile organic compounds: 0 %
Evaporation rate: Not applicable
Viscosity: >= 1,000,000 centipoise at 23
C
Percent Volatile: 0 % by weight
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10 Stability and Reactivity
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Conditions to Avoid:
Heat;
Store out of direct sunlight.
Sparks and/or Flames;
Avoid curing large quantities of material to prevent a premature
reaction (exotherm) with production of intense heat and smoke.
Materials to Avoid:
Strong oxidizing agents;
Hazardous Decomposition:
Aldehydes - During Combustion;
Chlorine - During Combustion;
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Hydrogen Chloride - During Combustion;
Hydrogen Cyanide - During Combustion;
Ammonia - During Combustion;
Oxides of Nitrogen - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization may occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Vapours released during curing may cause eye irritation.
Signs/symptoms may include redness, swelling, pain, tearing, and
blurred or hazy vision.
Effects from Skin Contact:
Moderate Skin Irritation: Signs/symptoms can include localized
redness, swelling, itching, and dryness.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
Effects from Inhalation:
Vapours released during curing may cause irritation of the
respiratory system. Signs/symptoms may include cough, sneezing,
nasal discharge, headache, hoarseness, and nose and throat pain.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, stomach upset, nausea, vomiting and diarrhea.
Sensitization Information:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
Carcinogenicity:
No data available.
Mutagenicity:
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No data available.
Reproductive Effects:
No data available.
Component Based Information:
No data available.
Product Based Information:
No data available.
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
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13 Disposal Considerations
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Product as Sold:
Dispose of completely cured (or polymerized) wastes in a sanitary
landfill. As a disposal alternative, incinerate uncured product in
an industrial or commercial incinerator in the presence of a
combustible material. Combustion products will include HCI.
Facility must be capable of handling halogenated materials.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transport Information
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Transportation of Dangerous Goods
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TDG Classification: Regulated Material.
Proper Shipping Name: SELF-HEATING SOLID, ORGANIC,
N.O.S.*
Technical Name: DICYANDIAMIDE AND
PARA-CHLOROPHENYL-DIMETHYLUREA
Class/Division: 4.2
UN Number: UN3088
Packing Group: II
Special Information:: Contact 3M for more information.
These transportation classifications are provided as a customer
service. As the shipper YOU remain responsible for complying with
all applicable laws and regulations, including proper
3M(TM) Scotch-Weld(TM) 2214 Regular Epoxy Adhesive Page 9 of 10
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transportation classification and packaging. 3M's transportation
classifications are based on product formulation, packaging, 3M
policies and 3M's understanding of applicable current regulations.
3M does not guarantee the accuracy of this classification
information. This information applies only to transportation
classification and not the packaging, labeling, or marking
requirements. The original 3M package is certified for Canadian
ground shipment only. If you are shipping by air or ocean, the
package may not meet applicable regulatory requirements.
International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: D2B
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
DSL - Domestic Substances List (Canada)
TSCA - Toxic Substances Control Act (USA)
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16 Other Information
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Reason for Reissue:
Added French translation to MSDS
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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